Table of Contents
- 1 What is sawhorse structure?
- 2 What is sawhorse projection formula?
- 3 Which is more stable staggered or eclipsed?
- 4 How is Newman projection different from sawhorse structure?
- 5 What is the difference between sawhorse projection and Newman projection?
- 6 What is Fischer projection formula?
- 7 Is gauche more stable than eclipsed?
- 8 Why staggered form is more stable than eclipsed?
- 9 How to draw sawhorse projection for butane conformer?
- 10 Is the Sawhorse representation the same as the Newman projection?
What is sawhorse structure?
Sawhorse projection: A representation of molecular structure, from an oblique angle. Somewhat similar to Newman and zig-zag (Natta) projections. The sawhorse projection is named after its similar appearance to a carpenter’s sawhorse. Sawhorse projection.
What is sawhorse projection formula?
A saw-horse formula is a diagram used to depict a specific conformation of a molecule. Sawhorse projection, allows better visualization of the three-dimensional geometry between adjacent carbon atoms. This projection is customarily used to show interactions between groups on adjacent carbon atoms in mechanisms.
What is sawhorse projection with example?
In a sawhorse projection, a molecule is viewed from an angle, rather than side-on. For example, imagine looking at model 1 of ethane below at an angle so that the carbon atom highlighted in red is further from you, and the carbon atom in grey is closer to you.
Which is more stable staggered or eclipsed?
hydrocarbons. …with respect to the other—the eclipsed conformation is the least stable, and the staggered conformation is the most stable. The eclipsed conformation is said to suffer torsional strain because of repulsive forces between electron pairs in the C―H bonds of adjacent carbons.
How is Newman projection different from sawhorse structure?
A sawhorse projection is similar to a Newman projection, but it shows the carbon-carbon bond that is hidden in a Newman projection. Just as with Newman projections, you can draw sawhorse projections in eclipsed and staggered conformations. Below is a sawhorse projection of the gauche conformation of butane.
Which Newman projection is most stable?
-Therefore, option A is most stable because the bulky groups (bromine) lie opposite to each other and form anti-staggered conformation. While in B and D, they are close to each other causing repulsion and less stability. Option C is eclipsed, so definitely high in energy and less stable than rest three conformers.
What is the difference between sawhorse projection and Newman projection?
What is Fischer projection formula?
A Fischer projection or Fischer projection formula is a convention used to depict a stereoformula in two dimension without destroying the stereochemical information, i.e., absolute configuration, at chiral centers.
What are the different types of projection?
This group of map projections can be classified into three types: Gnomonic projection, Stereographic projection and Orthographic projection.
- Gnomonic projection. The Gnomonic projection has its origin of light at the center of the globe.
- Stereographic projection.
- Orthographic projection.
Is gauche more stable than eclipsed?
The gauche form is less stable than the anti form due to steric hindrance between the two methyl groups but still is more stable than the eclipsed formations. Such an interaction is often referred to as a gauche-butane interaction because butane is the first alkane discovered to exhibit such an effect.
Why staggered form is more stable than eclipsed?
The increase in potential energy is due to the repulsion between electrons in the bond. This increase in the potential energy is known as the torsional strain. Thus, the staggered conformation is more stable than the eclipsed conformation because staggered conformation has no torsional strain.
How are sawhorse projections used in organic chemistry?
Sawhorse projections are the normal line structure molecules drawn usually without hydrogens. These can be converted into newman projections or other structures which show 3-dimensional representations of molecules.
How to draw sawhorse projection for butane conformer?
Exercise: Draw the sawhorse projection for the butane conformer shown below. Click on the tabs for hints. Identify the atoms that are in the plane of the page. Use Up/Down Arrow keys to increase or decrease volume. Rotate the structure downwards by 45 o, then towards you by 45 o. Use Up/Down Arrow keys to increase or decrease volume.
Is the Sawhorse representation the same as the Newman projection?
The sawhorse representation combines the wedge and dash model and the Newman projections. It extends out the bond on the Newman projection, like on a wedge and dash model, but keeps the bonds lined up so that we can see the interactions easier.
How to draw 3 chloro 2 butanol enantiomers?
Drawing each of the enantiomers of 3-chloro-2-butanol, we can examine some of the stability of each enantiomer.